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orthonormal basis SAM.

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The only possible measurement is between any two orthogonal states (an orthonormal basis).
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Any separable inner product space has an orthonormal basis.
en.wikipedia.org
If the vectors of an orthogonal basis are normalized, the resulting basis is an orthonormal basis.
en.wikipedia.org
Physicists commonly regard a density operator as being represented by a (possibly infinite) density matrix relative to some orthonormal basis.
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The result does not depend on the choice of orthonormal basis.
en.wikipedia.org
Within this orthonormal basis, the structure constants are then antisymmetric with respect to all three indices.
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For example, it is often desirable to compute an orthonormal basis for a space, or an orthogonal change of bases; both take the form of orthogonal matrices.
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Every symmetric matrix is thus, up to choice of an orthonormal basis, a diagonal matrix.
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A particular case is obtained when these vectors form an orthonormal basis, that is, they are all perpendicular to each other.
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The eigenstates have a physical meaning further than an orthonormal basis.
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