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Reaction overpotential can be reduced or eliminated with the use of electrocatalysts. en.wikipedia.org

This can cause a concentration overpotential at both electrodes. en.wikipedia.org

The overall overpotential is the summation of many individual losses. en.wikipedia.org

This activation energy is often related to an overpotential of a competing reaction. en.wikipedia.org

Bubble overpotential is a specific form of concentration overpotential in which the concentration of charge-carriers is depleted by the formation of a physical bubble. en.wikipedia.org

Each step is associated with multiple forms of overpotential. en.wikipedia.org

The exchange current density is the current in the absence of net electrolysis and at zero overpotential. en.wikipedia.org

The simpler two-electron reaction to produce hydrogen at the cathode can be electrocatalyzed with almost no overpotential by platinum, or in theory a hydrogenase enzyme. en.wikipedia.org

Different catalysts require unequal overpotential for this reduction reaction to take place. en.wikipedia.org

The activity of ions at the electrode surface changes when there is current flow, and there are additional overpotential and resistive loss terms which contribute to the measured potential. en.wikipedia.org

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